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368 results

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Page 1
Hexa-mu-acetato-chlorido-(mu-N,2-dioxodo-benzene-1-carboximidato)-mu(3)-oxido-tetra-iron(III)-water (1/1) and hexa-mu-acetato-(mu-N,2-dioxodo-benzene-1-carboximidato)fluorido-mu(3)-oxido-tri-pyridine-tetra-iron(III)-pyridine-water (1/1/0.24).
Ward CL, Allen MJ, Lutter JC. Ward CL, et al. Acta Crystallogr E Crystallogr Commun. 2021 Sep 14;77(Pt 10):1003-1009. doi: 10.1107/S2056989021009208. eCollection 2021 Oct 1. Acta Crystallogr E Crystallogr Commun. 2021. PMID: 34667627 Free PMC article.
The two mol-ecules are mostly isostructural, differing only by the torsion of the pyrine ligands and slight orientation changes in the acetate ligands. All of the iron(III) ions are in six-coordinate octa-hedral ligand field geometries but each one exhibits a …
The two mol-ecules are mostly isostructural, differing only by the torsion of the pyrine ligands and slight orientation changes in the ac …
A di-iron(III) mu-oxido complex as catalyst precursor in the oxidation of alkanes and alkenes.
Das B, Al-Hunaiti A, Carey A, Lidin S, Demeshko S, Repo T, Nordlander E. Das B, et al. J Inorg Biochem. 2022 Jun;231:111769. doi: 10.1016/j.jinorgbio.2022.111769. Epub 2022 Feb 17. J Inorg Biochem. 2022. PMID: 35287038 Free article.
The crystal structure of the complex reveals that each Fe(III) ion is coordinated by three nitrogen and three oxygen donors, two of which are the bridging oxido and acetate ligands. Employing H(2)O(2) as a terminal oxidant, 1 is capable of oxidizing a number of alkanes and …
The crystal structure of the complex reveals that each Fe(III) ion is coordinated by three nitrogen and three oxygen donors, two of which ar …
Phosphate binders for preventing and treating chronic kidney disease-mineral and bone disorder (CKD-MBD).
Ruospo M, Palmer SC, Natale P, Craig JC, Vecchio M, Elder GJ, Strippoli GF. Ruospo M, et al. Cochrane Database Syst Rev. 2018 Aug 22;8(8):CD006023. doi: 10.1002/14651858.CD006023.pub3. Cochrane Database Syst Rev. 2018. PMID: 30132304 Free PMC article.
The remaining studies evaluated comparisons between sevelamer (hydrochloride or carbonate), sevelamer plus calcium, lanthanum, iron (ferric citrate, sucroferric oxyhydroxide, stabilised polynuclear iron(III)-oxyhydroxide), calcium (acetate, ketoglutarate, car …
The remaining studies evaluated comparisons between sevelamer (hydrochloride or carbonate), sevelamer plus calcium, lanthanum, iron (ferric …
The fenton activity of iron(III) in the presence of deferiprone.
Devanur LD, Neubert H, Hider RC. Devanur LD, et al. J Pharm Sci. 2008 Apr;97(4):1454-67. doi: 10.1002/jps.21039. J Pharm Sci. 2008. PMID: 17724662
The partially coordinated [(deferiprone)(2)Fe(III)](+) complex is able to generate hydroxyl radicals in the presence of oxidants, whereas the fully coordinated [(deferiprone)(3)Fe(III)](0) complex is not. Hydroxyl radical production from iron(III)deferiprone complex …
The partially coordinated [(deferiprone)(2)Fe(III)](+) complex is able to generate hydroxyl radicals in the presence of oxidants, whereas th …
Iron(iii) bis(pyrazol-1-yl)acetate based decanuclear metallacycles: synthesis, structure, magnetic properties and DFT calculations.
Gajewska MJ, Bieńko A, Herchel R, Haukka M, Jerzykiewicz M, Ożarowski A, Drabent K, Hung CH. Gajewska MJ, et al. Dalton Trans. 2016 Sep 27;45(38):15089-15096. doi: 10.1039/c6dt02333a. Dalton Trans. 2016. PMID: 27722574
The synthesis, structural aspects, magnetic interpretation and theoretical rationalizations for a new member of the ferric wheel family, a decanuclear iron(iii) complex with the formula [Fe(10)(bdtbpza)(10)(mu(2)-OCH(3))(20)] (1), featuring the N,N,O tridentate bis( …
The synthesis, structural aspects, magnetic interpretation and theoretical rationalizations for a new member of the ferric wheel family, a d …
The synthesis, characterisation and application of iron(iii)-acetate complexes for cyclic carbonate formation and the polymerisation of lactide.
Driscoll OJ , Hafford-Tear CH , McKeown P , Stewart JA , Kociok-Köhn G , Mahon MF , Jones MD . Driscoll OJ , et al. Dalton Trans. 2019 Oct 14;48(40):15049-15058. doi: 10.1039/c9dt03327k. Dalton Trans. 2019. PMID: 31515544
Herein, we report the preparation, characterisation and catalytic applications of air-stable Fe(iii)-acetate complexes consisting of salan, salen and salalen ligand frameworks. ...X-ray diffraction confirmed the solid-state structures for eight of the complexes. These repr …
Herein, we report the preparation, characterisation and catalytic applications of air-stable Fe(iii)-acetate complexes consisting of …
Iron(III)-doped, silica nanoshells: a biodegradable form of silica.
Pohaku Mitchell KK, Liberman A, Kummel AC, Trogler WC. Pohaku Mitchell KK, et al. J Am Chem Soc. 2012 Aug 29;134(34):13997-4003. doi: 10.1021/ja3036114. Epub 2012 Aug 16. J Am Chem Soc. 2012. PMID: 22871140 Free PMC article.
To obviate this problem, silica nanoshells were tested for enhanced biodegradability by doping iron(III) into the nanoshells. Exposure of the doped silica to small molecule chelators and mammalian serum was explored to test whether the removal of iron(III …
To obviate this problem, silica nanoshells were tested for enhanced biodegradability by doping iron(III) into the nanoshells. …
Iron(III)-Mediated Oxysulfonylation of Enamides with Sodium and Lithium Sulfinates.
Kramer P, Halaczkiewicz M, Sun Y, Kelm H, Manolikakes G. Kramer P, et al. J Org Chem. 2020 Mar 6;85(5):3617-3637. doi: 10.1021/acs.joc.9b03299. Epub 2020 Feb 21. J Org Chem. 2020. PMID: 32013434
Moreover, the direct incorporation of sulfur dioxide into the sulfonylated products via organolithium chemistry has been achieved. The formed N-O-acetals are competent acylimine precursors. Their utilization as building blocks for the synthesis of biologically relevant bet …
Moreover, the direct incorporation of sulfur dioxide into the sulfonylated products via organolithium chemistry has been achieved. The forme …
Iron(III)/Copper(II)-Cocatalyzed Cycloaddition/[3,3]-Rearrangement/N-O Bond Cleavage To Prepare Polysubstituted Pyrrolizines from N-Vinyl-alpha,beta-Unsaturated Nitrones and Activated Alkynes.
Zou N, Jiao JW, Feng Y, Pan CX, Liang C, Su GF, Mo DL. Zou N, et al. Org Lett. 2019 Jan 18;21(2):481-485. doi: 10.1021/acs.orglett.8b03767. Epub 2019 Jan 10. Org Lett. 2019. PMID: 30628783
An efficient one-pot synthesis of polysubstituted pyrrolizines from N-vinyl- alpha,beta-unsaturated nitrones and activated alkynes through iron(III)/copper(II)-cocatalyzed [3 + 2] cycloaddition/[3,3]-rearrangement and sequential N-O bond cleavage was developed. The …
An efficient one-pot synthesis of polysubstituted pyrrolizines from N-vinyl- alpha,beta-unsaturated nitrones and activated alkynes through …
Achieving Selectivity for Phosphate over Pyrophosphate in Ethanol with Iron(III)-Based Fluorescent Probes.
Huang SY, Pierre VC. Huang SY, et al. JACS Au. 2022 Jun 25;2(7):1604-1609. doi: 10.1021/jacsau.2c00200. eCollection 2022 Jul 25. JACS Au. 2022. PMID: 35911450 Free PMC article.
The tetra- and pentadentate ligands enable anion recognition by the iron(III) center via its remaining one or two open coordination sites. ...Coordination of phosphate to the iron(III) center was confirmed by ATR-IR and (31)P NMR spectroscopy....
The tetra- and pentadentate ligands enable anion recognition by the iron(III) center via its remaining one or two open coordin …
368 results